Phenoxo-Bridged Dimeric Structure of Technetium (I) Tricarbonyl Complex with Schiff Base Ligand
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چکیده
منابع مشابه
Study the Interaction of Ni Complex of Tetradentate Schiff Base Ligand with HEN Egg White Lysozyme
AbstractInteraction of Ni complex(Salen= N, N´-ethylene bis(salicylideneimine)) with hen egg-white lysozyme (HEWL) was studied by absorption spectroscopy, competitive binding study and thermal denaturation study. The protein binding affinity of Ni complex was found to be (3.0×103M−1). The binding plot obtained from the absorption titration data gives a binding constant of 2.4 (± 0.3)×103 M...
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The reactions of 1 - chloro - 2 - nitro benzene with 2 - Amino thio phenol yield the 2 - ( ( nitro phenyl ) thio ) aniline and then 2 , 2' - thio dianiline of this compound was prepared . Also the symmetrical potentially pentadentate N 2 O 2 S Schiff base ligand 2 , 2' - ( ( ( thio bis (1 , 2 - phenylene ) ) bis ( azanilidene ) ) bis ( methenilidene ) ) diphenol ( H 2 L ) obtain by added salicy...
متن کاملstudy the interaction of ni complex of tetradentate schiff base ligand with hen egg white lysozyme
abstractinteraction of ni complex(salen= n, n´-ethylene bis(salicylideneimine)) with hen egg-white lysozyme (hewl) was studied by absorption spectroscopy, competitive binding study and thermal denaturation study. the protein binding affinity of ni complex was found to be (3.0×103m−1). the binding plot obtained from the absorption titration data gives a binding constant of 2.4 (± 0.3)×103 m-1. i...
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The formation of a borate-bridged dimeric aluminum Schiff-base compound [salen(Bu)Al]2O2BOMe [salen=N,N’-ethylenebis(salicylidenimine) (1) has been reported. Complex 1 crystallizes in a triclinic P space group with a=14.57, b=15.15, c=15.84 Å and a=96.92, b=90.82, g=105.538. The crystal structure shows the presence of a metaborate (MeOBO2 2– ) bridge between two five-coordinate aluminum atoms w...
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Here, new N,N′-dipyridoxyl(4,4''-diaminodiphenylether) Schiff-base ligand has been synthesized and characterized by IR, 1H NMR and mass spectrometry. Also, geometry optimization and theoretical assignment of IR spectrum of the ligand have been computed by employing density functional theory (DFT) method. Two pyridine rings and benzene rings in the bridge region are not in the same plane. The ca...
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ژورنال
عنوان ژورنال: Journal of Nuclear and Radiochemical Sciences
سال: 2005
ISSN: 1345-4749
DOI: 10.14494/jnrs2000.6.3_149